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Fluorescent photochromic molecules have two photocyclization states and the change between the fluorescent form and non-fluorescent form is reversible and depends on the wavelength of light. By placing these molecules in the vicinity of a silver nanowire, featuring the plasmon resonance, we can control the photoswitching properties of these emitters. In this work, we deposited a submicron droplet of molecules on one end of a nanowire and used focused laser to remotely change the photocyclization state of the molecule via surface plasmon polariton propagation. The effects observed for such a unique system can be applied for quantum optics and sensing.
Martyna Jankowska,Karolina Sulowska,Maciej Cwierzona,Saioa Cobo,Dawid Piątkowski, andSebastian Maćkowski
"Controlling fluorescence of photochromic molecules via plasmonic silver nanowire (Conference Presentation)", Proc. SPIE PC12396, Plasmonics in Biology and Medicine XX, PC1239605 (16 March 2023); https://doi.org/10.1117/12.2649852
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Martyna Jankowska, Karolina Sulowska, Maciej Cwierzona, Saioa Cobo, Dawid Piątkowski, Sebastian Maćkowski, "Controlling fluorescence of photochromic molecules via plasmonic silver nanowire (Conference Presentation)," Proc. SPIE PC12396, Plasmonics in Biology and Medicine XX, PC1239605 (16 March 2023); https://doi.org/10.1117/12.2649852