Decay Of The Second Order Susceptibility Of Poled PMMA Films Doped With An Azo Dye

Remi Meyrueix; Gerard Mignani

doi:10.1117/12.961415

22 December 1989 Decay Of The Second Order Susceptibility Of Poled PMMA Films Doped With An Azo Dye

Remi Meyrueix, Gerard Mignani

Proceedings Volume 1127, Nonlinear Optical Materials II; (1989) https://doi.org/10.1117/12.961415
Event: 1989 International Congress on Optical Science and Engineering, 1989, Paris, France

Abstract

The rotationnal diffusion of Disperse Red One dopant in PMMA is studied by electrooptical polarimetry. The temperature is varied from Tg to far below the secondary transition temperature Tβ. Above Tβ, disordering but also ordering of the dopant are possible. This rotationnal diffusion cannot be described by a diffusion coefficient and is strongly related to the free volume relaxation inside the polymer. The mobility is almost completly frozen under Tβ.

Citation Download Citation

Remi Meyrueix and Gerard Mignani "Decay Of The Second Order Susceptibility Of Poled PMMA Films Doped With An Azo Dye", Proc. SPIE 1127, Nonlinear Optical Materials II, (22 December 1989); https://doi.org/10.1117/12.961415

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