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Interlayer coupling in van der Waals heterostructures exhibits unique physical properties and presents a new pathway for diverse applications in materials science and photonics. Interestingly, photo-responsivity of graphene with semiconducting transition metal dichalcogenide (TMD) can be enhanced in the UV-visible range by interlayer charge/energy transfer. However, such an effect has been studied only for semiconducting materials.
In this work, we will discuss ultrafast hot-electron transfer in atomically thin metallic-layer VSe2/graphene heterostructures investigated by time-resolved pump-probe spectroscopy. Our experimental finding extends the concepts of conventional two-dimensional heterostructures to metallic-layer and can provide a new degree of freedom for designing novel functionalized materials and devices.
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Tae Gwan Park, Byong Ki Choi, Junho Park, Jungdae Kim, Young Jun Chang, Fabian Rotermund, "Ultrafast hot-electron transfer in metallic VSe2/graphene van der Waals heterostructures (Conference Presentation)," Proc. SPIE 11278, Ultrafast Phenomena and Nanophotonics XXIV, 1127804 (10 March 2020); https://doi.org/10.1117/12.2544768