The influence of the structure of phosphorus-based ligands on the stability of europium complexes using spectrophotometric titration

Tsagana B. Sumyanova; Nataliya E. Borisova; Gladiz G. Zakirova; Leonid A. Korotkov

doi:10.1117/12.2563625

9 April 2020 The influence of the structure of phosphorus-based ligands on the stability of europium complexes using spectrophotometric titration

Tsagana B. Sumyanova, Nataliya E. Borisova, Gladiz G. Zakirova, Leonid A. Korotkov

Author Affiliations +

Proceedings Volume 11458, Saratov Fall Meeting 2019: Laser Physics, Photonic Technologies, and Molecular Modeling; 114580W (2020) https://doi.org/10.1117/12.2563625
Event: Saratov Fall Meeting 2019: VII International Symposium on Optics and Biophotonics, 2019, Saratov, Russian Federation

Abstract

The influence of structure of the phosphine oxide ligands on stability of their complexes was studied by spectroscopic techniques. Surprising the electron donating methyl groups at phenyl rings of phosphine oxide groups lead to decrease of the stability of europium complex comparing with ubsubsituted one due to their sterical prevention of conjugation between phenyl rings and P=O-groups.. This unusual behavior was first time demonstrated by spectroscopic titration and Job’s plot analysis.

Citation Download Citation

Tsagana B. Sumyanova, Nataliya E. Borisova, Gladiz G. Zakirova, and Leonid A. Korotkov "The influence of the structure of phosphorus-based ligands on the stability of europium complexes using spectrophotometric titration", Proc. SPIE 11458, Saratov Fall Meeting 2019: Laser Physics, Photonic Technologies, and Molecular Modeling, 114580W (9 April 2020); https://doi.org/10.1117/12.2563625

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available