Structuring polymeric materials is important for almost all applications in microsystems engineering, microfluidics and microoptics. Especially rapid prototyping using direct optical printing methods has gained great importance, also for facilitating product development for microfluidic applications. However, the choice of materials is still limited. Polystyrene (PS) is the material of choice for medical, biological and biochemical applications due to its biocompatibility, optical transparency, surface properties and low costs. However, PS is usually structured using industrial polymer replication techniques like injection molding or hot embossing. So far, only little work has been done on rapid prototyping and direct printing of microfluidic chips in PS. In this work, we present a novel liquid polystyrene prepolymer, which can be photocured and structured on the microscale using direct lithography printing. Using this method microchannels with a minimum channel width of 500 µm have been fabricated. The cured PS shows material properties comparable to those of commercially available polystyrene.
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