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Vibrational super-equilibrium excitation and the simultaneous effect of rotational cooling have been measured for CO2 molecule desorption from a titanium foil surface using diode-laser spectroscopy. CO2 molecules were desorbed when the foil was heated by a current impulse. CO2 molecules binding energy with the titanium surface is equal to approximately 0.22 eV. The vibrational and rotational temperatures are equal to 100 +/- 10 K and 220 +/- 20 K accordingly, for the surface temperature range of 120 K - 180 K.
G. S. Baronov,D. K. Bronnikov, andS. A. Gavrikov
"Vibrational excitation and rotational cooling of CO2 molecules desorbed from titanium surface", Proc. SPIE 1724, Tunable Diode Laser Applications, (1 April 1992); https://doi.org/10.1117/12.58678
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G. S. Baronov, D. K. Bronnikov, S. A. Gavrikov, "Vibrational excitation and rotational cooling of CO2 molecules desorbed from titanium surface," Proc. SPIE 1724, Tunable Diode Laser Applications, (1 April 1992); https://doi.org/10.1117/12.58678