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Wide gap II-VI mixed crystals containing Mg and Be are recently studied extensively for their application in constructing blue-green laser diodes. This work deals with experimental study of optical modes in Zn1-xMgxSe and Zn1-xBexSe semiconductors using Raman scattering method. Measurements have been performed at room and liquid nitrogen temperatures for Zn1-xMgxSe crystals with Mg content in the range 0 < x < 0.34 and for Zn1-xBexSe with Be content in the range 0 < x < 0.26. From polarized Raman spectra longitudinal and transverse optical modes corresponding to ZnSe- and MgSe-like modes in Zn1-xMgxSe and to ZnSe- and BeSe-like modes in Zn1-xBexSe were determined. These lattice vibrations can be described by the modified random element isodisplacement model.
Miroslaw Szybowicz,Marek Kozielski,Franciszek Firszt,Stanislaw Legowski,Hanna Meczynska,Jacek Szatkowski, andWlodzimierz Paszkowicz
"Study of Zn1-xMgxSe and Zn1-xBexSe semiconducting crystals by Raman scattering", Proc. SPIE 3724, International Conference on Solid State Crystals '98: Single Crystal Growth, Characterization, and Applications, (24 March 1999); https://doi.org/10.1117/12.342994
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Miroslaw Szybowicz, Marek Kozielski, Franciszek Firszt, Stanislaw Legowski, Hanna Meczynska, Jacek Szatkowski, Wlodzimierz Paszkowicz, "Study of Zn1-xMgxSe and Zn1-xBexSe semiconducting crystals by Raman scattering," Proc. SPIE 3724, International Conference on Solid State Crystals '98: Single Crystal Growth, Characterization, and Applications, (24 March 1999); https://doi.org/10.1117/12.342994