Electrochromic effect in V-Mo-O xerogels

Vladimir V. Bondarenko; S. Grebinskij; S. Mickevicius; A. Kindurys; D. Senuliene; V. L. Volkov; G. C. Zakharova

doi:10.1117/12.417611

8 March 2001 Electrochromic effect in V-Mo-O xerogels

Vladimir V. Bondarenko, S. Grebinskij, S. Mickevicius, A. Kindurys, D. Senuliene, V. L. Volkov, G. C. Zakharova

Proceedings Volume 4318, Smart Optical Inorganic Structures and Devices; (2001) https://doi.org/10.1117/12.417611
Event: Advanced Optical Materials and Devices, 2000, Vilnius, United States

Abstract

In present paper is reported the first successful observation of the electrochromic effect of polyvanadium- molybdenum acid H₂V₁₀Mo₂O_{31+/- y}(DOT)nH₂O xerogels. Thin films of the investigated compound were produced by sol-gel technology. The transmission spectra were measured in the visible and infrared wavelength range. IN the all wavelength regions the transmission spectra changes when the dc electrical field was applied to the film. IN the visible wavelength range were observed the reversible changes of the film color. IR spectroscopy measurements of the films were carried out to obtain information about the water content in the film when the current flows through the sample. The electrochromic effect in the investigated compound is related with the proton motion through the xerogel that is acting by dc electrical field.

Citation Download Citation

Vladimir V. Bondarenko, S. Grebinskij, S. Mickevicius, A. Kindurys, D. Senuliene, V. L. Volkov, and G. C. Zakharova "Electrochromic effect in V-Mo-O xerogels", Proc. SPIE 4318, Smart Optical Inorganic Structures and Devices, (8 March 2001); https://doi.org/10.1117/12.417611

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