New materials for nonlinear optics

William E. Douglas; Larisa G. Klapshina; Vladimir Viktotovich Semenov; George A. Domrachev; Zhanna Y. Fominikh; Oleg Leonidovich Antipov; Andrey V. Afanas'ev; Alexander Sergeevich Kuzhelev; Andrey Petrovich Zinoviev; Anatoly Nikolaevich Rubinov; Boris A. Bushuk; Sergey B. Bushuk; Richard G. Jones; Robert E. Benfield; Alkay Mustafa

doi:10.1117/12.475912

24 July 2002 New materials for nonlinear optics

William E. Douglas, Larisa G. Klapshina, Vladimir Viktotovich Semenov, George A. Domrachev, Zhanna Y. Fominikh, Oleg Leonidovich Antipov, Andrey V. Afanas'ev, Alexander Sergeevich Kuzhelev, Andrey Petrovich Zinoviev, Anatoly Nikolaevich Rubinov, Boris A. Bushuk, Sergey B. Bushuk, Richard G. Jones, Robert E. Benfield, Alkay Mustafa

Author Affiliations +

Proceedings Volume 4751, ICONO 2001: Nonlinear Optical Phenomena and Nonlinear Dynamics of Optical Systems; (2002) https://doi.org/10.1117/12.475912
Event: XVII International Conference on Coherent and Nonlinear Optics (ICONO 2001), 2001, Minsk, Belarus

Abstract

A variety of novel materials has been synthesized including poly(ethynediyl-arylene-ethynediyl-silylene)s (PEAES) containing hypercoordinate silicon, and films of metal- containing polyacrylonitrile materials. The (chi) ⁽³) properties in various matrices have been investigated by various techniques such as DFWM and Z-scan. The (chi) ⁽³) values are outstandingly high; e.g. sol-gel films incorporating 5-14 mass percent PEAES show Re(chi) ⁽³) equals 3-9 X 10^-11 esu, and films of Cr-containing polyacrylonitrile materials synthesized by the polycyanoethylation reaction between acrylonitrile and Ar₂Cr show (chi) ⁽³) equals -2.5 X 10^-10 esu.

Citation Download Citation

William E. Douglas, Larisa G. Klapshina, Vladimir Viktotovich Semenov, George A. Domrachev, Zhanna Y. Fominikh, Oleg Leonidovich Antipov, Andrey V. Afanas'ev, Alexander Sergeevich Kuzhelev, Andrey Petrovich Zinoviev, Anatoly Nikolaevich Rubinov, Boris A. Bushuk, Sergey B. Bushuk, Richard G. Jones, Robert E. Benfield, and Alkay Mustafa "New materials for nonlinear optics", Proc. SPIE 4751, ICONO 2001: Nonlinear Optical Phenomena and Nonlinear Dynamics of Optical Systems, (24 July 2002); https://doi.org/10.1117/12.475912

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