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Phase-change materials (PCMs), capable of non-volatile electrically or optically induced transitions, are being actively explored as a promising option for use in silicon photonic neuromorphic integrated circuits and compact modulators in telecom networks to overcome the limitations in footprint and power consumption imposed by the utilization of weak and volatile thermo-optic effects in current architectures. We present the first-ever broadband measurement of the thermo-optic effect in a number of widely explored chalcogenide PCMs across visible to telecom frequencies. Our measurements show that beyond their non-volatile phase change properties, PCMs also possess giant switchable broadband thermo-optic coefficients.
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