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This study introduces an optical approach to enhance the open-circuit voltage (Voc) in organic solar cells (OSCs) characterized by high radiative recombination. By exploring various one-dimensional structurations of the OSC device, we reduce Boltzmann losses arising from the mismatch between absorption and emission cones. This innovative method leads to a significant Voc enhancement, achieving an increase of approximately 30 mV through optical means. Furthermore, our findings establish a novel route in the development of planar geometry single-junction solar cells, surpassing the power conversion efficiency values set by the Shockley-Queisser limit.
Francisco B Texca,Mariia Kramarenko, andJordi Martorell
"Enhancing the open-circuit voltage in organic solar cells through an optical route", Proc. SPIE PC13014, Photonics for Solar Energy Systems X, PC130140D (19 June 2024); https://doi.org/10.1117/12.3017220
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Francisco B Texca, Mariia Kramarenko, Jordi Martorell, "Enhancing the open-circuit voltage in organic solar cells through an optical route," Proc. SPIE PC13014, Photonics for Solar Energy Systems X, PC130140D (19 June 2024); https://doi.org/10.1117/12.3017220