In this study, we patterned structures composed of graphitic and silicon carbide nanocrystals by the laser-induced carbonization of polydimethylsiloxane. The average size of the observed silicon carbide nanocrystals varied depending on the energy per laser pulse, or pulse energy, used for patterning, where larger crystals were observed for structures patterned with higher pulse energies. Moreover, the electrical property of the patterned structure shifted from conductive to semiconductive, as the pulse energy for patterning increased. To the best of our knowledge, this is the first demonstration of the patterning of structures exhibiting measurable semiconducting properties by the laser-induced carbonization of polymers.
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