Correlation between Yb3+ optical properties and structural disorder of glass network has been investigated by using good
quality Yb-doped silica glasses fabricated by MCVD method. Absorption spectra strongly depend on the fictive
temperature, which is a good indicator of structural disorder in silica glass. Their dependences are affected by the
codopants (Al and F). Fictive temperature dependence of refractive index has been also elucidated.
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